isaac_newton wrote:ah - could you explain the difference for those of us wot are not clued up on these details?
Fast-burning powder apply all the force of the gases to the shell in very short period of time, with no additional presure afterward. So tthe shell is actually accelerated only on the relatively short part of its way through the barrel, and thus long-barreled guns are counterproductive. The pressure would quickly drop, and all remaining lenght of the barrel would provide nothing but friction, slowing shell down.
Slow-burning powder build up pressure more gradualky, so the shell is accelerated MUCH longer. So the gun could be made much longer to accelerate shell to higher velocities.