Quarthinos wrote:AirTech wrote:If you are making ammonia, making hydrazine, and then unsymmetrical dimethylhydrazine(UDMH) would be a small step. Add fuming red (or white) nitric acid and you get a blast suitable for launching a Titan missile (hello Mercury / Gemini / Soyuz). This is why the Titan is made from stainless steel, but does not require refrigeration (these are storable - if very nasty - propellants).
The main problem I see with this is that RFNA isn't really storable. You have to add some HF, otherwise the acid attacks the steel and corrodes it's way out of the container. WFNA has the same problem. I'm pretty sure you can't make F any easier that you can make Cl without electricity.
Granted, you could make the RFNA next to the launch pad, but that really doesn't scale very well.
(Read Ignition! for more details..)
I have a copy of Ignition by John Clark (its available on a couple of places on the internet)....
The question is how long you store it for. If you want it in the rocket for years, its an issue, but storing it in glass lined tanks and filling the rocket just before launch then their corrosive problems become academic. The other question is how many launches you are making one a year or one a day - the V-2's had no problem as they were filled just before launch from tanker trailers.
Other alternatives also include liquid oxygen and methane rockets but these require ignitors - which are basically small solid fuel rockets but these also need cryogenic tankers but if you are making them you already have the technology.
BTW the Russians used timber heat shields on the early capsules - charred hard wood works well as a thermal insulator.
The issue is that it is possible but is it worth doing? once the OBS is offline the technology in storage in Nimue's cave becomes a template for the future.