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Chemistry and misc. stuff concerning it.

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Re: Chemistry and misc. stuff concerning it.
Post by AirTech   » Tue Dec 16, 2014 8:14 am

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Graydon wrote:
Draken wrote:So there's no chance for rediscovery of modern alloys?


Aluminium, magnesium, and titanium are refined using electrochemistry; they're impossibly expensive to refine chemically. (The Emperor Napoleon had a set of 24 seatings of gold dinnerware and one aluminium seating for himself. There are some really gorgeous aluminium and gold parade helmets and such from that period, too; chemically refined aluminium is more expensive than gold.)

A whole lot of modern steels depends on having thermocouples (temperature sensors) and lasers (spectrographs) which depend on electricity and repeated iterations of pure materials for laser crystals, to provide process control. (Those cheap five dollar bread knives involve really consistent alloys.) Lots of modern steels pass through electric furnaces or are electrically impulse hardened in applications like saws, too.

Nickel-steel they've already got, it's being used for armor. Chromium uses electric furnaces for refining; don't know offhand about vanadium and molybdenum. But in general chemistry is all about electrons and benefits enormously from having electricity involved. No electricity will seriously matter to the progress of chemistry on Safehold.


Discovery is different from use of existing knowledge - the CoGA is in a hole because they don't have access to OWL and his online library and are therefore bumbling around in the dark. (You don't need to discover what you already know...)
Odd chemical pathways that where not exploited on Earth because either a marginally less efficient technology was already in widespread use (and thus had economies of scale) or didn't have an major application because the global technological path was different could be widely used on Safehold.
Composite structures are one example, why use titanium if you can use carbon fiber or Kevlar? (Or Steel Thistle reinforced plastics).
The plastics would be a little limited as the Polyolefines like high density polyethylene, polypropylene and their co-polymers use aluminium and titanium based catalysts (and tetra ethyl aluminum and titanium solutions are really fun to play with anyway). That said urethanes, phenolics and epoxies are possible in the thermosets and styrenes are relatively easy and the feed stocks will be coming out of the steel mills waste streams from the coke ovens and pickling baths.
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Re: Chemistry and misc. stuff concerning it.
Post by Captain Igloo   » Tue Dec 16, 2014 1:52 pm

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Graydon wrote:
Draken wrote:So there's no chance for rediscovery of modern alloys?


snipp

Nickel-steel they've already got, it's being used for armor. Chromium uses electric furnaces for refining; don't know offhand about vanadium and molybdenum. But in general chemistry is all about electrons and benefits enormously from having electricity involved. No electricity will seriously matter to the progress of chemistry on Safehold.


Simple chromium steel was one of the first alloy steels to be made. In a open hearth furnace by adding ferro-chromium. Same thing with vanadium. Most of the chrome-vanadium steel made was used for driving axles and other forgings for locomotives, automobile springs and axles, compressed air flasks, torpedo tubes, and gun forgings.

An important use of these steels was in armor plate. Thick armor was face hardened by a carbonizing process in cementation furnaces, but the body had the original composition, which contained about Mn .32% ; Ni 4.00% and Cr 2.00%. Medium armor from three to five inches in thickness was not face hardened, but was given good properties by proper heat treatment. This medium armor contained about Mn .34%; Ni .3.66% and Cr 1.45%. These steels were also used in the manufacture of most AP projectiles.
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Re: Chemistry and misc. stuff concerning it.
Post by 6L6   » Tue Dec 16, 2014 2:38 pm

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You are useing 2014 tech to guess at how Safehold can produce various materials but remember that the TFN set out in 2421 with Operation Ark. Through Owl the people of Safehold have access to two hundred years of tech development beyond present day. Who knows what shortcuts he can come up with.
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Re: Chemistry and misc. stuff concerning it.
Post by Captain Igloo   » Tue Dec 16, 2014 3:05 pm

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6L6 wrote:You are useing 2014 tech to guess at how Safehold can produce various materials but remember that the TFN set out in 2421 with Operation Ark. Through Owl the people of Safehold have access to two hundred years of tech development beyond present day. Who knows what shortcuts he can come up with.


You mean demon-spawned alchemy straight from the pit? :lol:
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Re: Chemistry and misc. stuff concerning it.
Post by TN4994   » Tue Dec 16, 2014 3:20 pm

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Captain Igloo wrote:
6L6 wrote:You are useing 2014 tech to guess at how Safehold can produce various materials but remember that the TFN set out in 2421 with Operation Ark. Through Owl the people of Safehold have access to two hundred years of tech development beyond present day. Who knows what shortcuts he can come up with.


You mean demon-spawned alchemy straight from the pit? :lol:

Or a Titan called Prometheus.
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Re: Chemistry and misc. stuff concerning it.
Post by SWM   » Tue Dec 16, 2014 4:05 pm

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6L6 wrote:You are useing 2014 tech to guess at how Safehold can produce various materials but remember that the TFN set out in 2421 with Operation Ark. Through Owl the people of Safehold have access to two hundred years of tech development beyond present day. Who knows what shortcuts he can come up with.

That is true, but it is pretty clear that David does not intend to introduce techniques that do not already exist in modern real life. He may (and has) introduced innovations that skip over steps that happened historically, but he has not and I assume will not introduce steps that would not be possible historically.
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Re: Chemistry and misc. stuff concerning it.
Post by 6L6   » Tue Dec 16, 2014 4:45 pm

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Did Jules Verne or Isaac Asimov write about techniques in use in their times? RFC does not have to be limited either.
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Re: Chemistry and misc. stuff concerning it.
Post by SWM   » Tue Dec 16, 2014 5:04 pm

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6L6 wrote:Did Jules Verne or Isaac Asimov write about techniques in use in their times? RFC does not have to be limited either.

Actually, yes, both did. Not in all of their books, but in some of them. Similarly, David Weber has, in some of his books, but not all of them. The Safehold books are some of them.

The point is that an author can choose to limit the technology to what is already known. That is what David has done so far with the technology introduced publicly on Safehold. Merlin and OWL are using and sharing advanced futuristic technology among the Inner Circle. But David Weber has clearly chosen, quite deliberately, to use only real technology and realistic technological leaps (given the assumption of guidance by those with advanced knowledge) in the development of Safehold in general.

In one way, he is presenting what it is possible to achieve quickly, given a specific starting point, and assuming guidance from advanced knowledge.
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Re: Chemistry and misc. stuff concerning it.
Post by Captain Igloo   » Tue Dec 16, 2014 5:17 pm

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6L6 wrote:Did Jules Verne or Isaac Asimov write about techniques in use in their times? RFC does not have to be limited either.


Jules Verne in "The Begum's Five Hundred Millions"
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Re: Chemistry and misc. stuff concerning it.
Post by Draken   » Tue Dec 16, 2014 7:14 pm

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We're drifting out of main topic. For sure they can't get any alloys with titanium or aluminium. What about using uranium and iridium instead. Steel enriched with iridium is one of hardest alloys ever created and it shouldn't be that hard to get, only issue could be mining iridium it's one of rarest elements. Uranium could be used as core for AP bullets it isn't quite dangerous when isn't enriched. What about coal based polymers and other materials.
Is there any info about rubber and knowledge about it's wonderful qualities? If so we could use at for tires and for balloons. Nitroglycerin shouldn't be that hard to get, only problem could be with stabilizing it, cus it could blow up at anytime.
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