Keith_w wrote:While Hydrogen would be a more effective lifting gas than hot air, there is a natural advantage to hot air - hydrogen needs to made, stored in stong ncontainers, transported and then used - probably just once. Hot air can be made on the spot where ever theirs something burnable, or if there is a politician handy.
Hydrogen can be made on the spot too, and given its difficulty in storage (and leaks from the balloon envelope), the earliest aeronauts usually did just that.
The usual technique consisted of zinc filings and acid. An alternative was town gas (also known as water gas or syn gas)- carbon monoxide and hydrogen produced by burning coal and then adding steam. (The second was quite common if your balloon was launching from a city with gas street lighting- but your balloon has to be significantly bigger due to reduced buoyancy.)