Here is a good reference on Jean's escape mechanism.
Forgot the link, damn it.
http://sci.esa.int/science-e/www/object ... ctid=50647The bottom line is that at 1,000 K which is the temp at the top of the thermosphere, rms for Oxygen molecules is 1 km/s while rms for hydrogen molecules is 4 km/s. While the rms of Hydrogen is far short of escape velocity, a significant fraction of molecules (1 in 10,000) exceed escape velocity. CO2 has a higher molocular mass than Oxygen but rms velocity is only marginally lower.
This suggests that heating theatmosphere (or a significant portion of it) to about 16,000 K would result in Oxygen having the same velocity profile as hydrogen at 1,000 K. However; at this temperature you will have mostly atomic oxygen so 10,000 K would be quite adequate.
An orbiting solar mirror of perhaps 1,000 km diameter that focuses sunlight onto a region of atmosphere a few kilometers in diameter would create a region of rapid cook off.
Last edited by namelessfly on Thu May 01, 2014 2:08 pm, edited 1 time in total.