namelessfly wrote:The difficulty of eliminating reducing agents such as free Iron in the biosphere that would react with free Oxygen is perhaps overestimated. The reaction rate between Iron and Oxygen at room temperature is rather low and only free iron close to the surface would be able to react with atmospheric Oxygen. The only problematic Oxygen sink would be dissolved free Iron in planetary Oceans.
Based on this reference here:
http://www.jstor.org/discover/10.2307/4 ... 4098169283The solubility of free iron in water is quite low. This is especially true if dissolved CO2 in the oceans is mi imized by stripping off a CO2 atmosphere prior to establishing an Oxygen atmosphere. Once the initial inventory of dissolved Iron is Oxidized, the limiting factor would be the rate at which new Iron is eroded and dissolved. Well tended biological processes would
probably do the job of maintaining the Oxygen supply but augmenting with continued industrial
processes might be needed.
Namelessfly is right, here. Under normal temperatures and pressures, oxygen sinks will not work fast enough to prevent a sufficient oxygen atmosphere from being produced.
Now, if you raise the temperature to several thousand degrees, the reaction rates will go sky-high. You would have a problem with oxygen sinks then. If you raise the temperature high enough, you will actually get oxides breaking down (as Namelessfly suggested with CO2). But when that atmosphere starts cooling off, it will rapidly combine with any available elements. And if you are doing this to the entire atmosphere, you can't really segregate the surface from the gasses.
But if your terraforming process doesn't require really high atmospheric temperatures, you should not have a problem with oxygen sinks, on the timescales of human civilization.